These were prepared through coupling of stannyl pyridine 266 with 2 chloro and bromo 4 substituted pyridine derivatives in presence of metal salts. Ligands 250 and 285 were evaluated in the borylation of m xylene and compared to the activity of the literature standard ligand 4,4′ di tert butyl 2 anabolic steroids,2′ bipyridine dtbpy 22. Chapter 4 describes the preparation of 2,4,6 substituted pyridine derivatives.
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